Xenon dioxydifluoride

Xenon dioxydifluoride
Names
IUPAC name
Difluoro(dioxo)xenon
Other names
Xenon(VI) dioxide difluoride
Identifiers
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10329748
PubChem CID
  • 23236530
InChI
  • InChI=1S/F2O2Xe/c1-5(2,3)4
  • O=[Xe](=O)(F)F
Properties
Chemical formula
F2O2Xe
Molar mass 201.288 g·mol−1
Melting point 30.8 °C (87.4 °F; 304 K)[1]
Structure
Crystal structure
Orthorhombic [2]
Molecular shape
Disphenoidal or seesaw [Sawhorse]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Xenon dioxydifluoride is an inorganic chemical compound with the formula XeO2F2.[2][1] At room temperature it exists as a metastable solid, which decomposes slowly into xenon difluoride, but the cause of this decomposition is unknown.[1]

Preparation

Xenon dioxydifluoride is prepared by reacting xenon trioxide with xenon oxytetrafluoride.[1]

XeO 3 + XeOF 4 2 XeO 2 F 2 {\displaystyle {\ce {XeO3 + XeOF4 -> 2XeO2F2}}}

References

  1. ^ a b c d Claassen, Howard H.; Gasner, Earl L.; Kim, Hyunyong; Huston, J. L. (July 1968). "Vibrational Spectra and Structure of XeO 2 F 2". The Journal of Chemical Physics. 49 (1): 253–257. Bibcode:1968JChPh..49..253C. doi:10.1063/1.1669818. ISSN 0021-9606.
  2. ^ a b Willett, R. D.; LaBonville, P.; Ferraro, J. R. (1975-08-15). "Normal coordinate treatment of XeO 2 F 2". The Journal of Chemical Physics. 63 (4): 1474–1478. Bibcode:1975JChPh..63.1474W. doi:10.1063/1.431510. ISSN 0021-9606.
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Xenon compounds
Xenon(0)
  • AuXe4(Sb2F11)2
  • XeH+
Xenon(I)
  • XeCl
  • XePtF6
  • XeRhF6
  • XeRuF6
  • XePuF6
Xenon(II)
  • XeF2
  • XeFPtF5
  • XeFPt2F11
  • Xe2F3PtF6
  • XeCl2
  • XeBr2
  • FXeONO2
  • Xe(NO3)2
Organoxenon(II) compounds
  • XeC6F5F
  • XeC6F5C2F3
  • XeC6F5CF3
  • Xe(C6F5)2
  • XeC6F5C6H2F3
  • XeC6F5CN
  • Xe(CF3)2
  • Xenon(IV)
    • XeO2
    • XeF4
    • XeOF2
    • N(CH3)4XeF5
    • XeCl4
    Organoxenon(IV) compounds
  • XeF2C6F5BF4
  • Xenon(VI)
    • XeO3
    • XeF6
    • XeOF4
    • H2XeO4
    • NaHXeO4
    • XeO2F2
    • (NO)2XeF8
    • CsXeF7
    • RbXeF7
    • Cs2XeF8
    • Rb2XeF8
    Xenon(VIII)
    • XeO4
    • H4XeO6
    • XeF8 (predicted)
    Category:Xenon compounds
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